Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7816920 | Organic Geochemistry | 2018 | 30 Pages |
Abstract
The composition and hydrogen isotope values of leaf wax components can be powerful tools in reconstructing past climate and environments. However, interpretation of past environmental conditions from such components in sediments is complicated by species-specific influences and there is a need to better understand how vegetation type affects leaf wax composition and isotope ratios in modern environments. In this study we analyzed leaf wax (n-alkane) distributions and hydrogen isotope values of plants from a high latitude ombrotrophic bog in northern Norway. The isotopic analysis of surface water was also conducted on samples from 15 lakes along a ca. 150â¯km transect to contextualize the bog water isotopic composition and constrain fractionation factors among n-alkane homologues. We identified 14 different plant types growing on the bog surface, including mosses, graminoids and other herbs, sub-shrubs and a tree. n-Alkanes from the leaves of the modern plants had average chain lengths from 25 to 30.5, with a variety of distributions, and with the dominant compound of longer chain lengths (C27, C29, or C31). δD values of n-C25 to n-C33 for the vegetation samples ranged from â197â° to â116â°, with an average of â162â°. The data also revealed that the δD values for the homologues for half of the vegetation types had ranges that were â¥20â°. Using the average isotopic value of bog water samples, â60â°, we calculated apparent fractionation factors that ranged from â66â° to â134â° (avg. â¯â108â¯Â±â¯22â°), similar to other sites across Europe and to a global data compilation. Our results demonstrate the range of species-specific influences on leaf wax composition and isotopic values at this site and presumably other ombrotrophic bog environments, and provide a dataset to help evaluate the influence of vegetation type on regional sedimentary leaf wax records.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Nicholas L. Balascio, William J. D'Andrea, R. Scott Anderson, Stephen Wickler,