| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7825848 | Progress in Polymer Science | 2018 | 25 Pages |
Abstract
Free or immobilized lipases and cutinases are the predominant biocatalysts in the relevant polymer families, being used in polycondensation as well as in ring-opening reaction schemes. The efficiency of the different biocatalytic processes is herein correlated to important process parameters, such as the enzyme and monomer type, the reaction temperature and time, the polymerization technique (solution or solvent-free), as well as the by-product removal method, e.g., application of vacuum, water absorption by molecular sieves, azeotropic distillation.
Keywords
EAPCPDOPHAPSAPLAHDLCOOHMWDPTCROPLLACLLPDLPPL1,4-CyclohexanedimethanolUDLSSPCLEA1,8-DiaminooctaneAspergillus niger lipase[C4mim][BF4]Mucor miehei lipasePolyhydroxyalkanoatest-BuOH[C4MIM][PF6]TSAs[η][C4mim][NTf2]l-glutamic acid diethyl esterLipase APA(s)PDIPBSPHBPCLTHFBiocatalysisTGAscCO2BDODEA1-Butyl-3-methylimidazolium hexafluorophosphate1-Butyl-3-methylimidazolium tetrafluoroborate1H NMR1,3-propanediol1,4-butanediolSupercritical CO2l-Malic acidEAMPseudomonas cepacia lipaseδ-valerolactoneε-CaprolactoneCross-linked enzyme aggregatesILSDESPELHICDLATert-butyl alcoholTetrahydrofuranEquilibrium constantMolecular weight distributionreaction rate constantDAOPolymerization degreeDDLTemperatureglass transition temperatureBoiling temperatureMelting TemperatureResponse surface methodologyRSMPseudomonas aeruginosaPseudomonas fluorescens lipaseSuccinic acidRhizomucor miehei lipasePorcine pancreatic lipaseIonic liquidsHLEMolecular weightweight-average molecular weightnumber-average molecular weightIntrinsic viscosityPoly(butylene succinate)Poly(lactic acid)Poly(ε-caprolactone)PolyamidesPoly(ethylene glycol)PolyestersPolyesteramidesPolyhydroxybutyrateBio-based polymersEnzymatic polymerizationSolid state polymerizationPEGCalbCandida antarctica lipase BCandida cylindracea lipaseHydroxyl groupsCarboxyl groups
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Aliki Douka, Stamatina Vouyiouka, Lefki-Maria Papaspyridi, Constantine D. Papaspyrides,