Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7832358 | Acta Physico-Chimica Sinica | 2006 | 4 Pages |
Abstract
On the basis of the approximation of harmonic oscillation between SC and S for the symmetric stretching vibration of the CS2+ ions, the Franck-Condon factors for the
CË2Σg+âBË2Σu+ transitions of CS+2 ions have been calculated using the potential curves and wavefunctions of the harmonic oscillator. The calculation results have been used for comparison with the photodissociation spectra via the
CË2Σg+âBË2Σu+ transition, and for estimating the validity of the rotation constants and the bond length of
CË2Σg+ state given in the previous studies. The photodissociation mechanism via the
CË2Σg+âBË2Σu+ transitions of CS+2 ions has also been discussed.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Yuchao Ma, Limin Zhang, Xiujuan Zhuang, Jinting Wang, Maoping Yang, Shuqin Yu,