Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7832916 | Applied Surface Science | 2018 | 23 Pages |
Abstract
In this work, a novel urchin-like CuCo2O4 directly grown on three-dimenstional (3D) Ni foam as a binder-free anode materials of lithium-ion batteries via one-step solvothermal method followed by subsequent annealing. The microstructure and phase composition were characterized systematically. The result indicated that the product at a calcination temperature of 550â¯Â°C yielded the most outstanding electrochemical properties with incredible reversible specific capacity of 1700â¯mAh/g after 100 cycles at 200â¯mA/g and extraordinary rate performance of 1250â¯mAh/g at 1000â¯mA/g. The likely contributing factors to the glorious electrochemical performance of the product were related to the unique urchin-like structure containing one-dimenstional (1D) nano-needles, which could tolerate the volume effect during the Li+ insertion/extraction process and provide more channels for the transmission of electron and ions, as well as the introduction of Ni foam accelerating the transmission rate of electron.
Related Topics
Physical Sciences and Engineering
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Physical and Theoretical Chemistry
Authors
Youpeng Li, Miao Liu, Shuang Hou, Pu Wang, Xuexue Pan, Meixiang Xie, Yongxin Chen, Lingzhi Zhao,