| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7833003 | Applied Surface Science | 2018 | 20 Pages |
Abstract
A hexadecane-1,1-bisphosphonic acid monolayer was grafted on the surface of muscovite mica via a simple self-assembled method. The result of AFM showed that the height of the bisphosphonate SAMs was about 2.40â¯nm, corresponding to both monolayer-like coverage and the hydrocarbon chain length. TOF-SIMS indicated that the reaction between bisphosphonic acid and silicon was took place on the surface of mica substrate. It can be proved from IR, AFM, XPS, and TOF-SIMS that the alkylbisphosphonate SAM was bonded to the mica with the mode of double-tridentate attachment. In addition, organobisphosphonate SAM possessed excellent orderliness and stability, which provides a theoretical basis for its efficient application in the field of organic modification.
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Authors
Li Guanghui, Zheng Shuilin, Bai Chunhua, Li Xingdong, Cheng Changmei,