Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7834004 | Applied Surface Science | 2018 | 9 Pages |
Abstract
High density gold nanostructures are grown by thermal deposition on flat and nanostructured polymeric templates by exploiting the extraordinarily low wettability of Au on polydimethylsiloxane (PDMS). Undulated PDMS templates are fabricated by replica molding process (REM) on “masters” prepared by defocused Ion Beam Sputtering (IBS). Closely packed and laterally disconnected Au nanostructures are grown at grazing incidence on the PDMS replica templates exploiting the shadowing instability. The peculiar nanocluster morphology determines a Localized Surface Plasmon Resonances (LSPR) which is tunable in the visible range by varying light polarization and metal dose. All samples exhibit a strong increase of the Surface Enhanced Raman Scattering (SERS) intensity with amplification factors exceeding 103.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Diego Repetto, Maria Caterina Giordano, Antonino Foti, Pietro Giuseppe Gucciardi, Carlo Mennucci, Francesco Buatier de Mongeot,