Article ID Journal Published Year Pages File Type
7839259 Journal of Electron Spectroscopy and Related Phenomena 2018 27 Pages PDF
Abstract
A theoretical study has been conducted on nondipole asymmetry parameters and angular distribution of Kr 1s1/2 and 4p3/2 photoelectrons with Dirac-Fock method based on the density matrix theory, with a focus on the impacts of nondipoles on the photoelectron angular distribution. The results show that the electric-dipole-electric-quadrupole E1 and E2 interference has a significant influence on the spatial angular distribution of Kr 1s1/2 and 4p3/2 photoelectrons. To be specific, the photoelectron characteristics relevant to the direction of the polarization vector of the incident light can be destroyed by the E1 and E2 interference. For the Kr 4p3/2 photoelectron, it is suggested that the non-dipole effects of photoelectron distribution be measured in two energy positions where the electric dipole β parameter equals to zero. Higher order nondipole effects are negligible according to the investigations. Our calculations consist well with the available experimental and theoretical results.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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