Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7839947 | Journal of Luminescence | 2018 | 28 Pages |
Abstract
At present, improving the sensitivity is one main object for optical temperature sensing. In this work, a series of Yb3+-Er3+ and Yb3+-Ho3+ doped Ca3La6Si6O24 (CLS) phosphors were designed by solid-state reaction method to develop new rare earth (RE) ions activated upconversion luminescence materials based on thermally coupled and non-thermally coupled levels of Er3+/Ho3+. For the CLS:0.6Yb3+,xEr3+ (0.03â¯â¤ xâ¯â¤â¯0.18) and CLS:yYb3+,0.03Er3+ (0.3â¯â¤ yâ¯â¤â¯1.2) samples, the relative intensities of Er3+ different emission peaks change with the RE ions concentrations, which was interpreted by the proposed cross-relaxation (CR) processes. For the CLS:0.6Yb3+,mHo3+ (0.03â¯â¤ m ⤠0.18) and CLS:nYb3+,0.03Ho3+ (0.3â¯â¤â¯nâ¯â¤â¯1.2) samples, the 5F5-5I8 transition intensity of Ho3+ shows a continuous decrease with increasing Yb3+ or Ho3+ concentrations by normalizing the (5F4,5S2)-5I8 transition of Ho3+, which was explained by the CR between Yb3+ and Ho3+. The temperature dependence of the fluorescence intensity ratio for Er3+ and Ho3+ emissions was discussed in detail. The relative and absolute sensitivities were compared by using thermally coupled and non-thermally coupled levels of Er3+ and Ho3+. The present investigation could be instructive to develop new luminescent materials with high sensitivity.
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Authors
Jia Zhang, Zhenghe Hua,