Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7842611 | Journal of Molecular Liquids | 2018 | 8 Pages |
Abstract
Graphitic-C3N4 (g-C3N4) nanosheets were synthesized successfully and characterized by SEM, TEM, FI-TR, XRD, BET and XPS. A series of experimental results for the removal of Pb(II) and Cd(II) from wastewater were investigated. The g-C3N4 nanosheets exhibited high adsorption capacity towards Pb(II) and Cd(II), which can reach 395.54Â mg/g and 206.40Â mg/g at TÂ =Â 333Â K, pHÂ =Â 6.3, CNaNO3Â =Â 0.01Â mol/L. The adsorption kinetics of Pb(II) and Cd(II) complied with the pseudo-second-order model. The Freundlich and Langmuir models were used to simulate the adsorption isotherms of Pb(II) and Cd(II), and the results revealed that the adsorption of Pb(II) on g-C3N4 nanosheets coincided with monolayer adsorption, while the Cd(II) on g-C3N4 nanosheets coincided with multilayer adsorption. The thermodynamic parameters (ÎG0Â <Â 0, ÎH0Â >Â 0) revealed that the adsorption process was a spontaneous endothermic process. The experimental results revealed that the as-prepared g-C3N4 nanosheets can be utilized as a friendly, efficient and economical adsorbent for the purification of wastewater.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Qing Liao, Shunrong Yan, Wensheng Linghu, Yuling Zhu, Runpu Shen, Feng Ye, Gaofeng Feng, Lijia Dong, Abdullah M. Asiri, Hadi M. Marwani, Di Xu, Xilin Wu, Xue Li,