Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7870897 | Materials Science and Engineering: C | 2007 | 4 Pages |
Abstract
The electron conductivity and photocurrent generation properties of a self-assembled monolayer (SAM) formed by a helical hexapeptide chemisorbed on an interdigitated gold microelectrode have been investigated by cyclic voltammetry and photo-electrochemical experiments. Cyclic voltammetry measurements show that the peptide forms a densely packed self-assembled monolayer on the gold surface. Peculiar photocurrent/voltage responses have been obtained for the modified electrode, indicating that a photoinduced electron transfer from excited tryptophan to gold significantly contributes to the conductive properties of the peptide SAM.
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Authors
Emanuela Gatto, Mariano Venanzi, Antonio Palleschi, Lorenzo Stella, Basilio Pispisa, Leandro Lorenzelli, Claudio Toniolo, Fernando Formaggio, Giovanni Marletta,