Synthesis, characterization, electrochemical behaviors and applications in the Suzuki-Miyaura cross-coupling reactions of N2S2O2 thio Schiff base ligand and its Cu(II), Co(III), Ni(II), Pd(II) complexes and their usage in the fabrication of organic-inorga

► Thio Schiff base ligand and its transition metal complexes were synthesized. ► Catalytic property of the ligand was determined with Suzuki coupling reactions. ► Electrochemical properties of L, Cu(L) were investigated with cyclic voltammetry. ► The fabrication of organic-inorganic hybrid devices using L and its Co(III), Ni(II) and Pd(II) complexes and their electrical properties have been reported.