Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7880958 | Acta Materialia | 2015 | 8 Pages |
Abstract
This study investigates the mechanism of the Ï-to-α phase transformation in a titanium-molybdenum alloy. Using aberration-corrected high annular angle dark-field scanning transmission electron microscopy and density functional theory (DFT), the authors demonstrate that the Ï-to-α phase transformation is mediated by vacancy ordering. Atomic resolution Z-contrast images display high- and low-contrast regions in a single Ï precipitate, and it was found that the low Z-contrast regions are composed of an unknown structure, which differs significantly from the Ï-phase crystal structure. DFT calculations show that the vacancies could be stabilized by Mo and should preferably be assembled with ordering. The relaxed Ï-phase structure with ordered defects explains the intricate atomic images in the low Z-contrast regions of the Ï phase. It was found that this distorted Ï phase with defects is similar to the hexagonal α-phase structure with vacancies. It was confirmed that these vacancies could easily be occupied by Ti atoms and could form a perfect α phase.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Sung-Hwan Kim, Sung Jin Kang, Min-Ho Park, Cheol-Woong Yang, Hu-Chul Lee, Heung Nam Han, Miyoung Kim,