Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7882241 | Acta Materialia | 2014 | 7 Pages |
Abstract
Oxide compositions of equimolar YO1.5 and TaO2.5 in the Y-Ta-Zr-O system have attractive properties for high-temperature applications, including as thermal barrier coatings. The effect of zirconia concentration, from 0 to 20Â mol.% cation, on the tetragonal-to-monoclinic phase transition has been studied using high-temperature X-ray diffraction, Raman spectroscopy and electron microscopy. The transformation is reversible and the temperature variation of an order parameter based on the spontaneous strain is consistent with the transformation being ferroelastic, a critical feature for toughening at high temperatures. The presence of twin domains further supports this conclusion. Additionally, stabilization of the tetragonal phase with increasing ZrO2 is evident from the amount of partially retained tetragonal phase at room temperature.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Samuel Shian, Pankaj Sarin, Mary Gurak, Mor Baram, Waltraud M. Kriven, David R. Clarke,