Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
78846 | Solar Energy Materials and Solar Cells | 2011 | 10 Pages |
New symmetrical low band-gap small molecule materials, DPP-bis[ter-3HT-TPA] and DPP-bis[ter-3HT] as novel derivatives of Diketopyrrolopyrrole–thiophene with/without triphenylamine (TPA) end group have been synthesized and characterized. And the effects of TPA moiety were investigated. Compared to DPP-bis[ter-3HT], DPP-bis[ter-3HT-TPA] shows red-shifted absorption and significantly higher molar absorption coefficient. And the HOMO level of DPP-bis[ter-3HT-TPA] is elevated than DPP-bis[ter-3HT]. Moreover, DPP-bis[ter-3HT-TPA] exhibited one order higher hole mobility than DPP-bis[ter-3HT], suggesting that TPA contributes to a better hole mobility. The bulk-heterojunction photovoltaic devices with DPP-bis[ter-3HT-TPA] showed better efficiencies than DPP-bis[ter-3HT], showing the best power-conversion efficiency (PCE) of 1.5% (±0.12) under 100 mW/cm2 with a short-circuit current (Jsc)=5.73 mA/cm2, a fill factor (FF)=0.45, and an open-circuit voltage (Voc)=0.59 mV.
Graphical AbstractNew symmetrical low band-gap small molecule materials, DPP-bis[ter-3HT-TPA] and DPP-bis[ter-3HT] as novel derivatives of Diketopyrrolopyrrole-thiophene with/without triphenylamine (TPA) end group have been synthesized and characterized. And the effects of TPA moiety were investigated. Ban-Seok Jeong, Hyunbong Choi, Nara Cho, Haye Min Ko, Woo cherl Lim, Kihyung Song, Jae Kwan Lee, Jaejung Ko.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights►New low band-gap small molecule material, DPP-bis[ter-3HT-TPA] as novel derivatives of Diketopyrrolopyrrole–thiophene with triphenylamine end group exhibited significantly enhanced hole-mobility. ► The triphenylamine motif for small molecule BHJ materials contributes to a better hole mobility. ► The triphenylamine motif plays an important role as effective electron-donating and hole transporting mediator in organic photovoltaics.