Article ID Journal Published Year Pages File Type
7886537 Ceramics International 2018 33 Pages PDF
Abstract
A new type of porous carbon/MnO2 composites, having bicontinuous structures, i.e., continuous channels and carbon skeletons, was prepared using a phase separation method, followed by a carbonization procedure and a subsequent redox reaction. In this work, such composite electrodes show a high specific capacitance of ca. 260 F g−1 at 0.5 A g−1 in 1 M Na2SO4 aqueous solution, a superior cycling stability (~80% retention after 2000 cycles) and a distinctive high-rate performance. Especially, unique bicontinuous structures endow such composites with a great specific capacitance of the constituent MnO2 (~1100 F g−1), very close to the theoretical value. These excellent electrochemical behaviors may render this material a promising candidate as high-performance electrodes in supercapacitors. Therefore, our findings suggest that the strategy for constructing bicontinuous hybrid electrodes represents an exciting direction for designing next-generation supercapacitors.
Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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