Article ID Journal Published Year Pages File Type
7886908 Ceramics International 2018 16 Pages PDF
Abstract
The orientation characteristics of the defect dipoles formed by acceptor ions (CuNb″′) and oxygen vacancies (VO
-
- ) in CuO-doped (K0.48Na0.52)0.96Li0.04Nb0.805Ta0.075Sb0.12O3 piezoceramics were investigated. The ferroelectric and piezoelectric properties of the ceramics were obviously affected by the defect dipoles which are oriented along with the domains when poled under a dc electrical field of 3.5 kV/mm at the temperature near TC. The poled ceramics with 1.0-3.0 mol% CuO displayed strong asymmetric P-E loops and a large internal bias field (Ei), 3.89-4.57 kV/cm, when polarized at the temperature near TC. The enhanced piezoelectric coefficient d33, 186-192 pC/N, was obtained for the ceramics poled near TC when 0.02 ≤ x ≤ 0.03. The ceramics with oriented defect dipoles showed a relatively good thermal stability of d33 until 180 °C.
Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
Authors
, , , , , ,