Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7887424 | Ceramics International | 2018 | 20 Pages |
Abstract
The mechanical properties of newly synthesized Ca2C3 and Ca2C under pressure have been studied by using the first-principles calculations with generalized gradient approximation. The equilibrium geometry, elastic stiffness constants, various moduli, and Pugh's ratio of the C2/m phase of Ca2C3 and the C2/m and Pnma phases of CaC2 are systematically studied. The elastic stiffness constants of C2/m-Ca2C3 under 0-30GPa, C2/m-Ca2C under 0-7.5Â GPa, and Pnma-Ca2C under 7.5-30Â GPa satisfy the BornâHuang mechanical criteria. The three phases of calcium carbides exhibit ductile characteristics. The surface constructions of bulk and Young's moduli illustrate the mechanical anisotropy of Ca2C3 and Ca2C. Our results are consistent with previously obtained experimental and theoretical data and have significant implications for the application of calcium carbides.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Hong Jiang, Wei Dong, Xiao-Xue Qu, Kuan Cao, Yue-Hua Su, Chao Zhang,