Article ID Journal Published Year Pages File Type
7892189 Composites Part A: Applied Science and Manufacturing 2015 9 Pages PDF
Abstract
In this paper, we studied the water transport in thermoset matrices. We used Fourier Transform Infrared analysis (FTIR) during sorption/desorption experiments to investigate the interaction between sorbed water and the epoxy network. Our results demonstrated that the polymer matrix undergoes hydrolysis. We found that the chemical species involved in the reaction process was the residual anhydride groups. These results support the physical basis of the three-dimensional (3D) diffusion/reaction model. We finally showed that this model is able to reproduce multi-cycle sorption/desorption experiment, as well as water uptake in hybrid metal/epoxy samples. We simulated the 3D distributions of the diffusing water and the reacted water.
Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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