Article ID Journal Published Year Pages File Type
7893452 Corrosion Science 2018 23 Pages PDF
Abstract
Copper exposed to pure, O2-free water for several months in glass- and metal-contained, well-controlled systems shows no evidence of corrosion, either through hydrogen evolution or through the occurrence of oxidized copper. The results contradict the interpretation of recent experiments where it has been claimed that copper corrodes in pure, O2-free water far above the very limited extent predicted by established thermodynamic data. Reasons for the different experimental outcomes are discussed. Experimental and theoretical efforts to identify hitherto unknown, potentially corrosion driving species of the Cu-O-H system and studies of copper/water surface reactions are reviewed as background for the present study.
Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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