Article ID Journal Published Year Pages File Type
7894004 Corrosion Science 2018 10 Pages PDF
Abstract
Time dependent experiments were carried out to study the corrosion behaviour of Super 13Cr martensitic stainless steel after immersion in a H2S-saturated solution. The Point Defect Model was employed to obtain key parameters. With increasing immersion time, the corrosion product layer thickened, but displayed a defective structure. The thickness of the barrier layer decreased with extending the H2S-exposure time, which notably lowered the corrosion resistance. The presence of the corrosion scale resulted in a thinner barrier layer in contrast to that without the scale. With/without the corrosion scale, no semi-conductivity and no passive region was observed for Super 13Cr after 96 h-immersion. The hydrogen ingress during H2S-exposure lowered the passivity of the bare alloy substrate.
Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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