Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7895201 | Corrosion Science | 2015 | 11 Pages |
Abstract
The effect of shot-peening on the oxidation in air of the Ni-based superalloy RR1000 has been investigated over the temperature range 700-800 °C. The surface oxide in both peened and un-peened conditions consisted of isolated grains of rutile on the outermost surface beneath which was a protective Ti-doped chromia scale. Internal oxidation of aluminium occurred within the alloy with the formation of alumina particles within a γⲠ(nominally Ni3(Al,Ti)) denuded zone but the morphology of the sub-surface oxides differed between the two surface conditions examined. The kinetics of thickening of the chromia layer were sub-parabolic in most cases but closely approached parabolic behaviour for the un-peened surface condition at 800 °C. An enhancement in the rate of chromia growth was found for both surface conditions compared with a Ti-free chromia layer. This enhancement has been attributed to increased Cr ion diffusion as a result of Ti-doping of the chromia layer but the effect is reduced over time because of Ti-depletion in the alloy. At 800 °C, in the un-peened condition, the reduction in growth rate with exposure time is much less marked and this effect seems to be associated with the formation of a (Ti,Ta)O2 phase beneath the chromia layer.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
S. Cruchley, M.P. Taylor, R. Ding, H.E. Evans, D.J. Child, M.C. Hardy,