Article ID Journal Published Year Pages File Type
7895559 Corrosion Science 2014 8 Pages PDF
Abstract
In the present study, two types of subscale Cr and Re accumulation found at scale/alloy interface of two batches of Co32Ni21Cr10Al3.5ReY alloys are described. During oxidation, one alloy developed a supersaturated Cr-Re rich layer and another formed Cr-Re precipitates beneath the oxide in the subscale region. Diffusional and thermodynamic modelling showed the accumulation is a result of decreasing Cr and Re chemical potentials with Al depletion. The observed difference in accumulation forms is caused by the different phases in two alloys, with the former being γ, β, α and σ and the latter having only γ, β and σ.
Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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