Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7897756 | Journal of the European Ceramic Society | 2018 | 27 Pages |
Abstract
This work determines the X-ray powder diffraction peak positions for trigonal GdF3 experimentally and using simulation. An oxyfluoride matrix glass-ceramic containing the inorganic compound GdF3 was synthesised by quench casting followed by controlled heat treatment. X-ray diffraction analysis was used to confirm the amorphous nature of the as-cast glass, and to identify the compounds crystallised in the glass-ceramic by heat treatment. A simulated powder diffraction pattern for trigonal GdF3 was calculated and used to confirm the identity of the compound crystallised in the glass-ceramic as being trigonal GdF3. Rietveld refinement of the structural model was performed using the measured diffraction pattern to accurately determine the unit cell parameters and asymmetric atomic coordinates. A simulated powder diffraction pattern was then calculated for trigonal GdF3 using the refined structural parameters.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
D. de Faoite, I. Tobin, A. Ulyanov, O.J. Roberts, B. Shortt, L. Hanlon, S. McBreen, K.T. Stanton,