Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7898414 | Journal of the European Ceramic Society | 2018 | 9 Pages |
Abstract
Although phase boundary engineering has made notable progress in improving the electrical properties of (K,Na)NbO3-based piezoceramics, lattice distortion and spontaneous polarization of multiphase coexisting systems are a few of the remaining concerns. Here, new research employing XRD Rietveld refinement was performed to explore crystal structures, phase fractions and atomic parameters of Fe2O3-added (0.995-x)K0.48Na0.52NbO3-xBi0.5Na0.5ZrO3-0.005BiScO3 ceramics. The distortion of the oxygen octahedron and the spontaneous polarization were presented. Central cation displacement provides a much larger contribution to polarization and the electric dipole moment in orthorhombic phase is much larger than that in tetragonal phase. Benefiting from tetragonal-orthorhombic phase coexistence and lattice distortion, optimized ferroelectric and piezoelectric properties (d33â¯â¼â¯381â¯pC/N, Prâ¯â¼â¯20.47â¯Î¼C/cm2) were obtained. The ceramic still holds a large d33 (313â¯pC/N) after up to 300â¯â of thermal annealing. A series of material constants was also calculated and compared to lead-based ones.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Laiming Jiang, Zhi Tan, Lixu Xie, Yueyi Li, Jie Xing, Jiagang Wu, Qiang Chen, Dingquan Xiao, Jianguo Zhu,