Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7898542 | Journal of the European Ceramic Society | 2018 | 8 Pages |
Abstract
Si-C-N nano-powders with tunable carbon content were synthesized through the reduction of silicon tetrachloride (SiCl4) and trichloromethylsilane (SiCl3CH3) solution by sodium in liquid ammonia. The nano-powders contain two domains of structure, Si-C-N amorphous or continuous random networks (CRNs), and free carbon. The carbon content in Si3+nCnN4 CRNs, is tunable from n = 0 to n = 1. Free carbon will appeared with the increase of the C/Si mole ratio when C/Si is higher than 1/4. The crystallization of amorphous Si-C-N powders occurs at temperatures ranging from 1300 °C to 1500 °C depending on the carbon content. The additive-free dense Si-C-N ceramics with relatively low porosity were fabricated by Spark Plasma Sintering (SPS).
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Qi Wang, Mei Yang, Jiusan Xiao, Shuqiang Jiao, Hongmin Zhu,