Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7898741 | Journal of the European Ceramic Society | 2018 | 7 Pages |
Abstract
Fe doped BaTiO3 ceramics with giant permittivity and low dielectric loss were synthesized in N2/H2 atmosphere started with BaTiO3 powders and iron powders. XRD analysis exhibited the tetragonal-pseudocubic phase transition when the Fe content is 3Â mol%. XPS spectra confirmed the iron oxides with mixed-valence structure of Fe2+/Fe3+, while Ti-ions maintain Ti4+3d0 states without any oxidization-reduction. For the case of ceramics with 5Â mol% Fe, the dielectric constant was 66,650 at 1000Â Hz at room temperature, 19 times higher than that of pure BaTiO3 ceramics, while the dielectric loss tangent was 0.13. Comparison with other giant-permittivity materials demonstrated the superior potential of present ceramics. First-principles calculations investigated the interfacial interaction of Fe-[TiO2] interface and Fe-[BaO] interface. Giant dielectric constant was induced by the interfacial polarization between insulating ferroelectrics and semiconducting iron oxides with mixed-valence states, as well as the contribution from the generated electron hopping conduction.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Bingcheng Luo, Xiaohui Wang, Enke Tian, Hongzhou Song, Qiancheng Zhao, Ziming Cai, Wei Feng, Longtu Li,