Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7898798 | Journal of the European Ceramic Society | 2018 | 7 Pages |
Abstract
La0.6Sr0.4Co0.2Fe0.8O3-δ-Ce0.9Gd0.1O1.95 (LSCF-CGO) nanostructured cathodes with different LSCF-content are prepared in a single step by spray-pyrolysis deposition, simplifying notably the fabrication process compared to the traditional methods. The phase formation, structure, microstructure and electrochemical properties of the cathodes are investigated as a function of the CGO-content and the temperature by using X-ray diffraction, electron microscopy and impedance spectroscopy. The addition of CGO to LSCF limits the grain growth, giving rise to fine particles of approximately 30 nm of diameter after sintering at 800 °C. A small particle size of 50 nm is retained even after sintering at 1000 °C. However, the polarization resistance, determined by impedance spectroscopy, is not significantly improved with the CGO-addition. The performance of these nanocomposite electrodes, investigated in NiOCGO anode-supported cells, shows an improved power density of 0.9 Wcmâ2 at 650 °C, compared to 0.56 Wcmâ2 for a conventional screen-printed cathode.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
L. dos Santos-Gómez, J.M. Porras-Vázquez, E.R. Losilla, F. MartÃn, J.R. Ramos-Barrado, D. Marrero-López,