Article ID Journal Published Year Pages File Type
7908019 Optical Materials 2017 7 Pages PDF
Abstract
Photoluminescent properties of nanocrystalline powders of the LiLa(PO3)4 system co-doped with Pr3+/Yb3+ or Tm3+/Yb3+ ions were reported. The powders were synthesized by precipitation method and annealed at 450 °C. Two series of the samples were prepared with 1 mol% of praseodymium or thulium ions and with various ytterbium content (from 2% up to 16%). Both the up- and downconversion energy transfers were studied, in particular, the spectra and kinetics of photoluminescence under blue (into Pr3+ or Tm3+ ions, respectively) and NIR (into Yb3+ ions) excitations. The possible mechanisms of energy migration were discussed. Higher ytterbium concentration resulted in higher energy transfer efficiencies for both tetraphosphate systems.
Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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