Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7921175 | Materials Chemistry and Physics | 2018 | 8 Pages |
Abstract
In this work, the structural modifications induced by introducing small amounts (1-4â¯mol%) of Al2O3 and B2O3 in low-Tg pyrophosphate glass composition have been investigated using advanced solid-state 1D/2D MAS-NMR techniques. The 31P{X} D-INEPT sequence was used to establish the heteronuclear correlations between the phosphate moieties (31P) and doping elements (Xâ¯=â¯27Al or 11B). The X{31P} REDOR and X/X DQ-SQ NMR techniques were implemented to find out the exact nature and chemical environment adopted by the doping elements within the glass matrix. The NMR analysis confirmed that majority of Al3+ ions entered into the phosphate network as six-coordinated species and all the B3+ ions entered as four-coordinated units. The combined NMR analyses revealed different insertion pathways of Al3+ ion and B3+ ion into the phosphate network. The findings of the study suggest that Al3+ ions attach purely with non-bridging oxygen of the phosphate network without breaking additional P-O-P bonds whilst B3+ ions interact with the network by breaking P-O-P linkages highlighting different chemical natures of these doping elements towards the interaction with phosphate units.
Keywords
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Physical Sciences and Engineering
Materials Science
Electronic, Optical and Magnetic Materials
Authors
P. Rajbhandari, L. Montagne, G. Tricot,