Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7923218 | Materials Chemistry and Physics | 2015 | 6 Pages |
Abstract
The zinc alkali pyrophosphate system has been investigated in order to produce glasses with low glass transition temperature (Tg < 400 °C) and high thermal and chemical stability. The (66-x)ZnO-xM2O-33.4P2O5 (with M = Na) composition line was first analysed to determine how the Zn2+/Na+ substitution impacts the macroscopic properties and glass stability. In a second time, the three alkali oxides Na2O, K2O and Li2O were mixed and used in combination with the optimum ZnO amount (46.6 mol%) to investigate the mixed alkali effect. Finally, comparison with other low Tg systems from the literature proves the relevancy of that system for the development of low-Tg and stable glasses.
Related Topics
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Authors
P. Rajbhandari, L. Montagne, G. Tricot,