Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7923341 | Materials Chemistry and Physics | 2014 | 6 Pages |
Abstract
To minimize pyroelectric effects while keeping high piezoelectric effects in relaxor-PbTiO3 single crystals, the crystallographic orientation dependence of the pyroelectric and piezoelectric coefficients were investigated for binary (1 â x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-PT), ternary (1 â x â y)Pb(In1/2Nb1/2)O3-yPb(Mg1/3Nb2/3)O3-xPbTiO3 (PIN-PMN-PT) and Mn-doped PIN-PMN-PT single crystals with the “4R” multidomain state. The secondary pyroelectric coefficients were calculated from the thermodynamic inter-relationship between the piezoelectric, elastic, and thermal expansion coefficients, being on the order of (1.16-1.23) Ã 10â4 C mâ2 Kâ1 for binary crystals and (0.97-2.03) Ã 10â4 C mâ2 Kâ1 for ternary ones. The primary pyroelectric coefficients were -(6.73-6.84) Ã 10â4 C mâ2 Kâ1 and â(5.44-6.43) Ã 10â4 C mâ2 Kâ1 for binary and ternary crystals, respectively. The pyroelectric coefficients could be reduced by matrix rotation, but at the cost of decreasing longitudinal piezoelectric coefficients d33. Of particular interest is that the maximum piezoelectric coefficients d24â at θ = ±55o and d34â at θ = ±35o by a counterclockwise rotation of θ about the X axis (θ is the rotation angle about the coordinate axes), or d15â at θ = ±55o, and d35â at θ = ±35o by a counterclockwise rotation the Y axis, were found on the order of 3000 pC Nâ1. The corresponding pyroelectric coefficients could be reduced by â¼20%. The reduced pyroelectric coefficients that can contribute to decrease undesirable output signals, together with the high piezoelectric coefficients, enable relaxor-PT crystals as favorable candidates for high-sensitivity piezoelectric sensors.
Related Topics
Physical Sciences and Engineering
Materials Science
Electronic, Optical and Magnetic Materials
Authors
Yanxue Tang, Zongyang Shen, Shujun Zhang, Wenhua Jiang, Jun Luo, Thomas R. Shrout,