Article ID Journal Published Year Pages File Type
7923816 Materials Chemistry and Physics 2011 11 Pages PDF
Abstract
▶ Al2O3 and Al2O3-TiO2 (molar ratio Al/Ti = 2, AT2) mixed oxides were pore-filling impregnated to obtain Pd, Pt and Pd-Pt catalysts with ∼1 wt% nominal metal loading. ▶ Reduced catalysts were tested in the 4,6-dimethyl-dibenzothiophene hydrodesulfurization (HDS). ▶ In Pd-containing materials, TiO2 incorporation into the alumina support was favorable to the catalytic activity of noble metal catalysts. ▶ Enhanced intrinsic activity (per exposed metallic site) was obtained in Pt-containing catalysts supported on the AT2 mixed oxide. ▶ Yield to different products over various catalysts seemed to be strongly influenced by metallic particles dispersion.
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Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
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