Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7924104 | Materials Science and Engineering: B | 2018 | 9 Pages |
Abstract
Proton-conducting polymer electrolytes consisting of borotungstic acid (BWA) and polyacrylamide (PAM) were developed. The addition of BWA to PAM progressively improved the electrolyte conductivity. The as-fabricated BWA-PAM electrolyte exhibited a high ionic conductivity of ca. 27â¯mSâ¯cmâ1, but suffered from low shelf life due to poor water retention. With the modification of 10â¯wt% phosphoric acid (H3PO4), a longer shelf life and improved ionic conductivity of ca. 30 mS cmâ1 were achieved. A ternary electrolyte composition of 75BWA-PAMâ¯+â¯10% H3PO4 was identified to have a high conductivity and good shelf life. At BWA content greater than 75â¯wt%, the addition of H3PO4 led to an undesirable phase separation within the electrolyte. The ternary 75BWA-PAM+ 10% H3PO4 electrolyte was used to assemble solid cells with CNT-graphite electrodes. The cells exhibited 11.2â¯mFâ¯cmâ2 at 50â¯mVâ¯sâ1 and high rate performance at 1â¯Vâ¯s-1. The cells also retained â¥90% of their initial capacitance and maintained ca. â85° phase angle after 10,000 charging-discharging cycles at 6â¯Aâ¯gâ1.
Keywords
Related Topics
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Materials Science
Electronic, Optical and Magnetic Materials
Authors
Yee Wei Foong, Keryn Lian, Donald Kirk, Steven Thorpe,