Article ID Journal Published Year Pages File Type
7924124 Materials Science and Engineering: B 2018 10 Pages PDF
Abstract
(LixNa1−x)6Mg(SO4)4 ceramics denoted as LNMSx (x = 0.1, 0.3, 0.5, 0.7 and 1 mol%) were obtained via the solid state reaction method. The refinement of the structural parameters using the Fullprof software by the Rietveld method confirmed that the Li+ dopant can replace the sodium in this structure with a slight increase in the lattice parameters. The spectroscopic studies revealed the vibrational mode of the sulfate groups. Electrical conductivity, activation energies, modulus and dielectric properties were studied by impedance spectroscopy in the [553-733 K] temperature range. Results show that the materials present a semiconductor ionic character with 1D conduction by means of migration of cation mobile in the system. Conductivity decreases when the Li+ dopant content x increases. The electrochemical studies show that LNMSx (x = 0.5) has the highest electrical conductivity that can be proposed as a good electrolyte material for lithium or sodium batteries applications.
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Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
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