Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7934711 | Progress in Natural Science: Materials International | 2018 | 6 Pages |
Abstract
Perovskite-type borohydride, NH4Ca(BH4)3, is considered as a promising hydrogen storage material due to its high gravimetric hydrogen capacity (15.7â¯wt%). In this work, the dehydrogenation performance and reaction pathway of NH4Ca(BH4)3 have been systematically investigated. It is found that the initial decomposition temperature is only 65â¯Â°C, suggesting a low thermodynamic stability of NH4Ca(BH4)3. The desorption kinetics conducted by differential scanning calorimetry (DSC) indicates that the activation energy of decomposition is about 226.1â¯kJ/mol. The dehydrogenation pathway of NH4Ca(BH4)3 characterized by fourier-transform infrared spectroscopy (FTIR) and solid-state nuclear magnetic resonance (NMR) shows a stepwise decomposition process, in which the initial dehydrogenation is due to destabilization of H+ in NH4 and H- in BH4 followed by the subsequent dehydrogenation steps arising from the decomposition of homologous NH3BH3 and the final decomposition of Ca(BH4)2 at a high temperature, respectively.
Related Topics
Physical Sciences and Engineering
Materials Science
Electronic, Optical and Magnetic Materials
Authors
Chengguang Lang, Yi Jia, Jiangwen Liu, Hui Wang, Liuzhang Ouyang, Min Zhu, Xiangdong Yao,