| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 7952844 | Nano Energy | 2018 | 32 Pages |
Abstract
The FePc-based nanostructures âare firstly synthesized via the graphene-assisted colloid chemical reaction. The experimental results of MALDI-TOF MS, SEM, TEM, FT-IR, Raman, XPS, XANES and EXAFS prove the axial covalent bonding between FePc and RGO via FeâOâC bond after the interruption of CâOâC bond, which results in the formation of Fe(II)Pc/Fe(III)Pc/RGO nanostructures. Compared to the commercial Pt/C and other FePc-based nanomaterials, the optimal Fe(II)Pc/Fe(III)Pc/rGO nanostructure exhibits better ORR activity in alkaline solution, revealing the importance of the synergistic catalysis of five- and four- coordinated Fe atoms as well as carbon substrate for ORR.282
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Authors
Jia Guo, Xiaomei Yan, Qin Liu, Qiang Li, Xiao Xu, Longtian Kang, Zhanmin Cao, Guoliang Chai, Jun Chen, Yaobing Wang, Jiannian Yao,