Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
79656 | Solar Energy Materials and Solar Cells | 2011 | 14 Pages |
We describe the synthesis of two novel poly(1,4-arylene-2,5-thienylene)s P1 and P2 containing benzo[c][2,1,3]thiadiazole monomeric units via Suzuki–Miyaura polymerization of a thiophene diboronic ester with aryl diiodides. The use of a catalyst complex consisting of Pd(OAc)2 in combination with the electron-rich biaryl phosphine S-Phos resulted in efficient polymerization reactions. The polymers synthesized, P1 and P2, were characterized by UV–vis spectroscopy and cyclic voltammetry. Theoretical calculations and electrochemical measurements on P1 suggested a favorable position of the molecular orbitals for employment in polymer solar cells in combination with PCBM. Devices containing P1:PCBM 1:2 in the active layer showed an efficiency of 1.2% by simple spin casting from chloroform.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► New donor polymers P1–P2 are synthesized via Suzuki polycondensation of a thiophene diboronic ester. ► P2 is a copolymer alternating distorted and planar repetition units. ► UV–vis and electrochemistry on the two polymers confirmed their suitability for solar cells application. ► Polymers are further studied through DFT in vacuo calculations. ► Polymers photovoltaic outcomes are investigated.