Microstructure evolution, B2 grain growth kinetics and fracture behaviour of a powder metallurgy Ti-22Al-25Nb alloy fabricated by spark plasma sintering

A powder metallurgy (P/M) Ti-22Al-25Nb (at%) alloy was prepared by spark plasma sintering of pre-alloyed powders at 1000 °C/80 MPa/10 min. The solution treatments of the P/M Ti-22Al-25Nb alloy were conducted at a temperature range of 940-1030 °C at 30 °C intervals and holding times of 10 min, 30 min, 60 min, and 120 min. The effects of the solution temperature and the holding time on the microstructure evolution, B2 grain growth behavior, phase transition, tensile mechanical properties, and fracture behavior of the P/M Ti-22Al-25Nb alloy were systematically evaluated using optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction, and tensile tests. The results indicated that the microstructure and mechanical properties were closely linked to the solution temperature and the holding time. The effect of the holding time and the solution temperature on the B2 grain growth is well described by Beck's equation and Hillert's equation, respectively. The tensile tests showed that the tensile properties of the solution-treated P/M Ti-22Al-25Nb alloy were mainly affected by the number of O phases in the interior of the B2 grains and the phase transition degree of the α2 phase at the grain boundary. The P/M Ti-22Al-25Nb alloy solution-treated at 940 °C/10 min exhibited the best mechanical properties at room temperature with a yield strength, tensile strength, and elongation of 867.8 MPa, 949.5 MPa, and 7.4%, respectively. A phase transition model of the α2 phase was established. In addition, a tensile fracture model of the P/M Ti-22Al-25Nb alloy solution-treated under different conditions was established.