Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7988659 | Intermetallics | 2014 | 5 Pages |
Abstract
The β-phase Zn4Sb3 has attracted much attention because of its high thermoelectric performance in the intermediate temperature range thanks to disorder in the Zn lattice site. In this work are presented structural, thermal, electric and thermoelectric characterization of Zn4Sb3 pure and Ag, Al doped, prepared by a simple synthesis. Structural and microstructural analyses reveal homogeneous one-phases having compositions in agreement with the nominal ones. After thermoelectric characterization, Ag doping results mostly effective in lowering the resistivity and Seebeck coefficient value, by introducing holes in the system. On the other hand, the Al substitution yields a very small decrease of the Seebeck coefficient but, at the same time, a significant decrease of the thermal conductivity mainly due to the depressed phonon contribution. The thermal conductivity behavior is the main responsible for the good thermoelectric performances of (Zn0.99Al0.01)4Sb3, whose thermoelectric figure of merit reaches the encouraging value of 0.23 at 260 K.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Riccardo Carlini, Daniele Marré, Ilaria Pallecchi, Riccardo Ricciardi, Gilda Zanicchi,