Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7990037 | Journal of Alloys and Compounds | 2018 | 29 Pages |
Abstract
Developing anode materials that have high safety and high performance is essential for their application in Li ion batteries. Ternary phase Li4Ti5O12/rutile/anatase (N-LTO/A/R) nanocomposites that have abundant phase boundaries and structure defects are prepared via solvothermal synthesis and following calcination under an Ar/NH3 atmosphere. With the introduction of multiple phases and defects, the as-prepared ternary phase nanocomposites display excellent lithium storage capability in a Li half-cell as well as in full-cell batteries. The nanocomposites deliver a reversible specific capacity of 149.0â¯mAh gâ1â¯at a current density of 10â¯Aâ¯gâ1 and maintain about 85% of the specific capacity after 800 cycles at a higher rate of 5â¯Aâ¯gâ1 for the Li half-cell. Even in the Li ion full-cell, the as-prepared nanocomposites deliver specific capacities of 210 and 124â¯mAh gâ1â¯at current densities of 0.05 and 1â¯Aâ¯gâ1, respectively. The extraordinary electrochemical performance of the N-LTO/A/R nanocomposites is attributed to the nanostructures, phase boundaries, presence of structure defects, and larger specific surface area, which favor facilitating lithium ion diffusion and electron transfer. This study shows that the ternary phase nanocomposites are very promising as a high-performance anode in lithium ion batteries.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Meng Qin, Zhongjing Hao, Yueming Li, Di Liu, Shimin Liu, Peng Li,