Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7991626 | Journal of Alloys and Compounds | 2018 | 30 Pages |
Abstract
Copper oxide nanofilms can be fabricated on Cu foam by a simple electrochemical anodization process. However, it is difficult to obtain single-phase nanofilms that consist only of Cu2O or CuO. In this work, we present a modified anodization process that includes (NH4)6Mo7O24·4H2O in the electrolyte solution, and prepare single-phase CuO nanofilms grown directly on Cu foam. The surface morphologies of the CuO nanofilms are greatly dependent on the concentration of (NH4)6Mo7O24·4H2O included in the electrolyte solution during the anodization process, and accordingly present nanodots, nanoflakes, nanosheets, and/or nanobelts. The synthesis mechanism for CuO nanofilms is discussed in detail. The as-fabricated single-phase CuO nanofilms can be directly employed as electrodes that exhibit good supercapacitive performance, with an areal capacitance greater than 600â¯mFâ¯cm-2â¯at a current density of 1â¯mAâ¯cmâ2 in a 2â¯M KOH aqueous solution. Moreover, the single-phase CuO nanofilm electrodes also demonstrate excellent long term cycling stability with about 94% retention of the initial areal capacitance after 10,000 charge/discharge cycles. The results demonstrate that the CuO nanofilms prepared on Cu foam by our modified anodization process are promising electrode materials for high-performance flexible supercapacitors.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Xia Shu, Yan Wang, Jiewu Cui, Guanqing Xu, Jianfang Zhang, Wanfen Yang, Mingfeng Xiao, Hongmei Zheng, Yongqiang Qin, Yong Zhang, Zhong Chen, Yucheng Wu,