Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7992100 | Journal of Alloys and Compounds | 2018 | 24 Pages |
Abstract
Porous hollow Mg0.6Ni0.4O has been fabricated by simple solvothermal method and removed the template by calcining. Afterward, taking advantage of liquid infiltration method, we have successfully synthesized hollow Mg0.6Ni0.4O/S as positive material for Li-S battery with a sulfur loading of 59.9â¯wt%. Porous hollow structure not only promoted the electron transfer, but also mitigated the expansion of element sulfur in the process of charging and discharging. Under a current density of 200â¯mAâ¯gâ1, the reversible capacity was up to 912â¯mAh gâ1 after 65 cycles with a high rate performance, coulombic efficiency and a capacity retention of 98%. Especially, at a higher current density of 4000â¯mAâ¯gâ1, the reversible capacity maintained at 174.5â¯mAh gâ1 after 500 cycles. The excellent electrochemical performance was owe to Mg0.6Ni0.4O alleviating polysulfide dissolution in electrolyte and had unique catalytic effect on the Li/S redox reactions.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Lixin Zhang, Shaomei Zhang, Hongfang Jiu, Na Ren, Liya Jiang, Qi Wang, Xiaomin Wang,