Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7994210 | Journal of Alloys and Compounds | 2018 | 44 Pages |
Abstract
Spectroscopic investigation of Dy3+ doped Ca3(Nb,Ga)5O12 (CNGG) and Ca3(Li,Nb,Ga)5O12 (CLNGG) single crystals were performed in order to assess their potential as laser materials for yellow emission. Dy:CNGG and Dy:CLNGG single crystals were grown by the Czochralski method and investigated by high-resolution spectroscopic measurements for the first time. The Judd-Ofelt intensity parameters for the f-f transitions of Dy3+ in CNGG and CLNGG single crystals, were used to determine radiative transition rates Ar, branching ratios β, and radiative lifetime Ïr of the fluorescent Dy3+ levels. Based on low temperature absorption and emission spectra, partial energy levels diagram of Dy3+ doped CNGG and CLNGG single crystals were obtained. The emission cross-sections for the 4F9/2 â 6H13/2 transition of special interest for laser application were determined. The room temperature decay curves were analyzed through the framework of Inokuti-Hirayama (I-H) model and the results shows that electric dipole-dipole interaction are responsible for the energy transfer processes between Dy3+ ions in CNGG and CLNGG single crystals.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
C. Gheorghe, S. Hau, L. Gheorghe, F. Voicu, M. Greculeasa, M. Enculescu, K.N. Belikov, E. Yu. Bryleva, O.V. Gaiduk,