Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7995602 | Journal of Alloys and Compounds | 2016 | 5 Pages |
Abstract
The effects of Nb substitution on the solubility range, lattice parameters, and thermoelectric properties of CrSi2 with a C40-type structure have been investigated. Polycrystalline samples of Nb-substituted Cr1âxNbxSi2 (0 â¤Â x â¤Â 0.15) have been prepared by a two-step arc-melting process, followed by spark plasma sintering. XRD patterns confirm that single-phase Cr1âxNbxSi2 is obtained in the composition range 0 â¤Â x â¤Â 0.10. As x increases from 0 to 0.10, the a- and c-axis lengths increase linearly. For x > 0.10, the a- and c-axis lengths do not obey Vegard's rule. The electrical conductivity of Cr1âxNbxSi2 (0 â¤Â x â¤Â 0.10) increases with increasing x, although the Seebeck coefficient gradually decreases with increasing x over the entire temperature range. In addition, the total thermal conductivity decreases with increasing x, owing to the reduction in lattice thermal conductivity. As a consequence, the dimensionless figure-of-merit ZTmax increases from 0.16 (x = 0) at 600 K to 0.20 (x = 0.05) at 700 K.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Hiroki Nagai, Tomohisa Takamatsu, Yoshihiko Iijima, Kei Hayashi, Yuzuru Miyazaki,