Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7995771 | Journal of Alloys and Compounds | 2016 | 33 Pages |
Abstract
Pristine and carbon-coated Li4Ti5O12 nanosheets are synthesized by a hydrothermal process, followed by calcination at 750 °C for 10 h. The structural properties of the as-prepared composites are characterized systematically by X-ray diffraction (XRD), Raman spectra, scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM) and N2 adsorption-desorption analysis, respectively. Electrochemical lithium insertion/extraction performances are evaluated by the galvanostatic charge/discharge tests, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV), respectively. In comparison, Li4Ti5O12@C exhibits higher specific capacity, better rate capability and capacity retention than the pristine Li4Ti5O12. Analysis from the electrochemical measurements indicates that the enhanced electrochemical performances Li4Ti5O12@C might be attributed to the shorter Li-ion diffusion distance, lower charge-transfer resistance, better electrode kinetics and lower activation energy as a result of thinner nanosheet and the presence of carbon layer.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Zhiya Lin, Weibo Zhu, Zhisheng Wang, Yanmin Yang, Yingbin Lin, Zhigao Huang,