Insulator-metal transition in deep Sr-vacant spin-orbit Mott insulator S2IrO4

Sr2IrO4 exhibits a novel insulating state assisted by spin-orbit interactions. A series of polycrystalline samples of Sr2−xIrO4 have been synthesized. It is found that deep Sr-vacancies of Sr2−xIrO4 greatly reduce the rotation of IrO6 octahedral, and more importantly, a significant structural change occurs around x = 0.48 in both the lattice constants and the Ir−O2 bond length. An insulator-metal transition (IMT) appears and a non-Fermi-liquid metallic electronic state has been proved at x > 0.48 in Sr2−xIrO4. Furthermore, a sudden drop emerges of the localization temperature T0 and the antiferromagnetic (AFM) transition temperature TN in Sr1.5IrO4, together with the Curie-Weiss temperature reversing its sign. These abrupt changes are closely related with the reduction of the rotation crystal structure.