Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7997412 | Journal of Alloys and Compounds | 2016 | 22 Pages |
Abstract
Metallic antimony (Sb) is one promising candidate as anode material for sodium-ion batteries (SIBs) due to its high theoretical capacity of 660Â mAh/g. However, the electrochemical formation of Na3Sb alloy makes it will suffer from tremendous volume variation during Na-uptake/release cycling and hence poor practical Na-storage properties. The incorporation of reduced graphene oxide (rGO) should be one effective strategy to overcome this issue. Herein, it is excitingly discovered that in-situ preparation micro/nanocomposite composed of Sb and rGO has played an effective role on improving Na-storage performance, especially fast energy storage and cycle life. The in-situ-prepared micro/nanocomposite (I-Sb/rGO) can deliver a superior capacity of 112Â mAh/g even at an ultrahigh current density of 6Â A/g compared to the ex-situ-prepared one (E-Sb/rGO). And it also exhibits outstanding cycle life with a residual capacity of 173Â mAh/g after 150 cycles at current density of 0.5Â A/g, much higher than that (36Â mAh/g) of the ex-situ one. Those enhanced performance can be attributed to the advanced in-situ-prepared process.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Fang Wan, Hong-Yan Lü, Xiao-Hua Zhang, Dai-Huo Liu, Jing-Ping Zhang, Xiaoyan He, Xing-Long Wu,