Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7997903 | Journal of Alloys and Compounds | 2015 | 52 Pages |
Abstract
We present in situ small-angle neutron scattering results for two flexible metal-organic frameworks (MOFs). The figure shows that for one (NiBpene, high CO2 adsorption) the intensity of the Bragg peak for the expandable d-spacing most associated with CO2 adsorption varies approximately with the isotherm, while for the other (NiDBM-Bpy, high CO2 selectivity) the d-spacing, itself, varies with the isotherm. The cartoons show the proposed modes of structural change.220
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
A.J. Allen, L. Espinal, W. Wong-Ng, W.L. Queen, C.M. Brown, S.R. Kline, K.L. Kauffman, J.T. Culp, C. Matranga,