Article ID Journal Published Year Pages File Type
7997903 Journal of Alloys and Compounds 2015 52 Pages PDF
Abstract
We present in situ small-angle neutron scattering results for two flexible metal-organic frameworks (MOFs). The figure shows that for one (NiBpene, high CO2 adsorption) the intensity of the Bragg peak for the expandable d-spacing most associated with CO2 adsorption varies approximately with the isotherm, while for the other (NiDBM-Bpy, high CO2 selectivity) the d-spacing, itself, varies with the isotherm. The cartoons show the proposed modes of structural change.220
Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
Authors
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