Article ID Journal Published Year Pages File Type
7998986 Journal of Alloys and Compounds 2015 25 Pages PDF
Abstract
We report the results of 57Fe Mössbauer spectroscopy study, complemented by first-principles energy-band structure and the hyperfine-interaction parameters calculations, of a recently discovered layered iron oxyselenide Na2Fe2Se2O. It is confirmed that Na2Fe2Se2O is a Mott insulator. It is demonstrated experimentally that Na2Fe2Se2O orders antiferromagnetically with the Néel temperature TN=74.8(2) K and with the Fe magnetic moment of 3.0(1) μB. The calculated hyperfine-interaction parameters are in good agreement with the corresponding experimental parameters. The Debye temperature of Na2Fe2Se2O is found to be 274(3) K.
Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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