Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
7999248 | Journal of Alloys and Compounds | 2015 | 32 Pages |
Abstract
The effect of cobalt doping on the structural and magnetic properties of polycrystalline Sm0.5Ca0.5Mn1âxCoxO3 (0 ⩽ x ⩽ 0.20) has been studied. Powder X-ray diffraction (XRD), dc magnetization and ac susceptibility measurements have been performed. The orthorhombic deformation caused by the Jahn-Teller (JT) effect can be counterbalanced by Co3+ doping. Meanwhile, antiferromagnetic (AFM), spin glass (SG) and phase separation (PS) ferrimagnetic states appear, successively, with the increase of x. The critical slowing down model and the dynamic scaling equation were applied in some samples. The existence of two distinct length scales for SG and finite FM (ferromagnetic) order is the source of the progressive deviation which exists in the dynamic scaling fitting for x = 0.05. Moreover, the small peaks at â¼8 K in Ïâ³(T) curves are believed to be induced by the canted moments of Mn ions as observed in Nd2/3Ca1/3MnO3.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Xiaolong Xu, Yu Li, Feifei Hou, Qian Cheng, Runzhou Su,